reddish tint arising from a maximum or excess of manganese; or,
if the glass be previously colourless, it will cause a greenish tint
to appear, which the manganese had dissipated: therefore, carbon would
seem to be a neutralizer of oxygen, and practically a dissipater of the
colour, caused by manganese. But should the Glass thus lowered in tint
be re-melted, or only softened by the drop pincher, in moulding it into
prisms or ornamental drops, the reddish tint will again appear; as if
(which is probably the case,) the carbon received in the annealing had
again been dissipated, and replaced by oxygen in the process of pinching.
However massive may be the piece of flint Glass, which is the medium
of these changes, the purple tint of the manganese, the greenish hue from
iron, (the impurities of the lead or other ingredients,) not only adhere
to the surface of the Glass, skin-deep, but extend to every particle of
the central and general mass. That these alternate changes are the result
of two antagonist chemical agents appears confirmed by the fact of
Glassmakers resorting to carbon for the neutralization of the manganese
reddish tint, when in excess in the fluid Glass; this is done by agitating
it in the pot with a wooden pole or burning staff, the carbon from
which is found to have the effect of dissipating the manganese colour.
An excess of nitrate of potash or soda has somewhat the same colouring
effect as manganese, arising probably from its abundance of oxygen.*
* The Glassmaker is well aware, when
mixing materials for filling the pots a second time in the same week,
consisting chiefly of cullet, or broken Glass, and saltpetre or other
alkali, with but little if any new or virgin
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